METHANOLASAFUELFORTRANSPORTATION-GLOBALPERSPECTIVE全球视角下甲醇作为交通燃料进展ChrisChatterton,ChiefOperatingOfficer克里斯查特顿首席运营官2019METHANOLFUELANDVEHICLEAPPLICATIONANSSYSTEMFORUM甲醇燃料及甲醇汽车应用体系建设论坛XIAN,CHINA中国西安September5-6th,2019WWW.METHANOL.ORGContents-AboutMI关于MI目录-LowCarbonandRenewableMethanolCapacity低碳绿色甲醇-MethanolFuelforRoadTransportation道路交通用甲醇燃料-MethanolasMarineFuel船用甲醇燃料-MethanolforFuelCells燃料电池甲醇燃料WWW.METHANOL.ORGABOUTMI关于我们WWW.METHANOL.ORGMEMBERS会员Tier1EcofuelTier2Tier3Tier4WWW.METHANOL.ORGLOWCARBONANDRENEWABLEMETHANOLCAPACITY低碳绿色甲醇WWW.METHANOL.ORGWHERREENIESWMAEBTLHEAPNAOTLHPWRAOYDS可UC再E生D?途径RenewableelectricitySustainableJ可再生电力biomass(residues,MSW,etc)可持续生物质(辐射、都巿固体废物等）FermentationGasificationKraftprocess发酵气化牛皮纸浆制造法BiogasElectrolysisCarboncapture沼气电解碳捕获BiomethaneSyngasSyngas生物甲烷合成气合成气Reactor&distillationReactor&distillation反应器和蒸馏反应器和蒸馏Source:TheMethanolInstituteandQafaqBio-methanolRenewablemethanol来源:全球甲醇行业协会和卡塔尔燃料添加剂生物甲醇可再生甲醇公司WWW.METHANOL.ORGWHEARNEEISFFMICEITEHNATNEONLERPRGOYDCUACRERDIE?R高效能源载体电、氢液体储存介质LIQUIDSTORAGEMEDIUMFORELECTRICITY&HYDROGENC02CaptureRecycledthroughtheatmosphereEmissionsC02捕获在大气中循环排放SynthesisMETHANOLApplications合成甲醇forpureCO2纯CO2的应用Reformer重整器H2GenerationMethanolforstoringanddistributingH2生成electricityandhydrogen.用于储存和分配电和氢的甲醇otherapplicationsMethanolCH30Hhas,onavolumebasis,40%moreH2thanliquidhydrogenat-其他应用253°C,and140%moreH2thancompressedhydrogenat700bars.在-253°C时，甲醇CH3OH中的H2体积比液氢高40%,在700bar时的H2含量比压缩氢高140%。WWW.METHANOL.ORGVARIOUSSTAGESOFDEVELOPMENT发展的不同阶段WHEREISMETHANOLPRODUCED?MethanolcategoryCommercialFeasibilityandR&DStoppedorOn-hold甲醇的类别商业化可行性及研发停止或暂停Bio-methanol•BioMCN(NL)•Biogo(GER)•BioMCN(glycerine)(NL)生物甲醇•BioMCN（荷兰）•Biogo（德国）•BioMCN（丙三醇）（荷兰）•Enerkem(CAN)•Enerkem(NL)•Chemrec(SE)•Enerkem（加拿大）•Enerkem（荷兰）•Chemrec（瑞典）•NewFuel(DEN)•LowLandsMethanol(NL)•RangeFuels(USA)•NewFuel（丹麦）•LowLandsMethanol（荷兰）•RangeFuels（美国）•Oberon(USA)•Södra(SE)•SchwarzePumpe(GER)•Oberon（美国）•Södra（瑞典）•SchwarzePumpe（德国）•NREL(USA)•VärmlandsMetanol(SE)Renewablemethanol•CRI(IC)•NREL（美国）•VärmlandsMetanol（瑞典）可再生甲醇•CRI（冰岛）•HeveskesEnergy(NL)•Woodspirit(NL)•Innogy(GER)•HeveskesEnergy（荷兰）•Woodspirit（荷兰）•Innogy（德国）•bseEngineering(GER)WWW.METHANOL.ORGHybridmethanol•GPIC(BAH)•bseEngineering（德国）混合甲醇•GPIC（巴哈马）•BlueFuelEnergy(CAN)•Methanex(CAN)•BlueFuelEnergy（加拿大）Lowcarbonmethanol•Methanex（加拿大）•CRI(CN/GER)低碳甲醇•QAFAC(QAT)•CRI（中国/德国）•QAFAC（卡塔尔）•MefCO2(GER)•SABIC(KSA)•MefCO2（德国）•SABIC（沙特阿拉伯）•Infraserv(GER)•Infraserv（德国）•LiquidWind(SE)•LiquidWind（瑞典）•PortofAntwerp(BE)•PortofAntwerp（比利时）•STEAG(GER)•STEAG（德国）•SwissLiquidFuture(CH)•SwissLiquidFuture（中国）•ZASt(GER)•ZASt（德国）•USC(USA)•USC（美国）•Gensoric(GER)•Gensoric（德国）•Neo-H2(USA)•Neo-H2（美国）•HaldorTopsoe(DEN)•HaldorTopsoe（丹麦）•OPTIMeoH(GER)•OPTIMeoH（德国）•Carbon2Chem(GER)•Carbon2Chem（德国）•FRESME(SE)•FRESME（瑞典）•NCF(CN)•NCF（中国）•GasTechno(USA)•GasTechno（美国）•MaverickSynfuels(USA)•MaverickSynfuels（美国）METHANOLFUELFORROADTRANSPORTATION道路交通用甲醇燃料WWW.METHANOL.ORG甲醇是多用途的燃料资源Methanolisaversatilefuelsource•2017年全球7500万吨甲醇消费中，能源和燃料应用占比40%Outofthe~75millionmetrictonsofmethanolsoldgloballyin2017,energyandfuelusesrepresent40%oftotaldemand•从2009-2017，直接甲醇燃料掺混年均增速约23%From2009-2017,directmethanolfuelblendinghasincreasedatanannualrateofnearly23%燃料FUELS技术TECHNOLOGIES•Neatfuel纯甲醇•SI&CIengines点燃和•Lowblends低比例混压燃发动机合•Turbines燃气轮机•Highblends高比例混•Fuelcells燃料电池•Industrialboilers工业锅合•GEM汽油乙醇甲醇三炉•CookStoves民用灶具混合•MTBE甲基叔丁基醚市场细分SEGMENTS•Biodiesel生物柴油•DME&OME二甲醚•Road&non-roadtransportation道路和非道路应用•Power&heatgeneration发电和供热和聚甲氧基二甲醚•Marine船舶•MTG甲醇制汽油WWW.METHANOL.ORG全球汽油中甲醇含量GlobalMethanolContentinGasoline综合过去三年世界油品质量调查，截止到2019年1月Source数据来源:SGSINSPIREWWW.METHANOL.ORGFuelBlending•3%甲醇掺掍汽油M3MethanolFuelBlendinginRegularGasolineinInitiativesEurope甲醇燃料掺混•欧洲标准汽油标准（EN228）允许添加最高3%的甲醇3%methanolallowedinEUEN228gasolinestandard目前在英国和北欧国家CurrentlyinUKandNordicCountries•可再生甲醇的燃料应用RenewableMethanolinfuelpool•甲醇用于乙醇汽油中作为助溶剂，如巴西和意大利的A20Methanolinethanolgasolineasco-solvent,likeBrazilandA20inItaly•在一些国家发现超过汽油允许添加量的甲醇EvenhighercontentthanallowedlimitsfoundinmanycountriesWWW.METHANOL.ORG德国C3项目GermanC3Mobility•C3：闭环碳循环C3MobilityforClosedCarbonCycle•德国能源局和汽车工业领导下的公共部门和私有企业合作Jointpublic/privatepartnershipwithGermanMinistryoftheEconomyandEnergyandGermanautomotiveindustry•2年，2400万欧元Two-year,€24millionprogramWWW.METHANOL.ORG德国C3项目GermanC3MobilityWWW.METHANOL.ORGIndia:RoadmaptoMethanolEconomyUnion&RoadTransportM印SF度В：ЕД甲Е醇ТС经В济ОЮ规划ДЕ蓝ЯТ图ЕЛЬНОСТЬВMinisterNitinGadkariБ•ОЛSЕepЕteЧmЕbМer62001С5,ТNРIАTIНAАaХyoМgfИorРmАedthe工会和道路交通部长MethanolEconomyExpertGroupWWW.METHANOL.ORG•2015年9月，NITIAayog成立甲醇经济专家组•2018MethanolM15Guidelinespublished•2018年发布了《甲醇汽油M15指南》•2018IRClasspublishedGuidelinesforMethanolFueledVessels•2018年IRClass发布了《甲醇燃料船舶指南》•LaunchingProjects:•启动项目：oM15fuelblendingM15o混合燃料oMethanolM100gensets,busesandtruckso甲醇M100发电机，公交车和卡车orailwayengines火车头oinlandwaterways内陆水路ocookstoves烹调用炉oindustrialboilers工业锅炉METHANOLASMARINEFUEL船用甲醇燃料WWW.METHANOL.ORGPRACTICALSOLUTION实用的解决方案Fuelvalvetrain(GVU)Methanolservicetank燃油气门机构(GVU)甲醇供给箱Methanol•Multi–fuelengineswillbethesupplysystemnormgoingforward甲醇供应系统多燃料发动机将成为未来的主流ME-LGIMethanolcargofuelpump•Methanolcanbereadilyandenginesafelyappliedinbothnewbuild甲醇货物燃料泵andconversionME-LGI引擎在建造和改造过程中可以轻松而安全地应用甲醇Double-waitedpipes双壁管Single-walledpipes单壁管•Methanolcanbeapracticalsolutionfordualfuelapplications,toincludeotheralternativefuelssuchasLPGandLNG甲醇可带来实用的双燃料组合应用解决方案，搭配的燃料包括替代燃料，如液化石油气和液化天然气WWW.METHANOL.ORGMETHANOL/WATERBLENDING(EMULSIFICATION)甲醇/水混合（乳化）DIref.DI参考编号DIref.DI参考编号FinalTier-traeFinalTier-trae最后阶段-trae最后阶段-traeNOX(corrtolSO)[g/kWh]NOX(根据lSO)[g/kWh]SFOC(corr.tolSO)[g/kWh]SFOC(根据tolSO)[g/kWh]Load[%]Load[%]负载[%]负载[%]•Approximately25-40%waterisaddedtothemethanoltoachieveanew,TierIIIsolution向甲醇中添加大约25-40%的水，获得的新溶液可满足欧洲氮氧化物第三阶段排放要求•NOxdecreasesalmostlinearlywithwatercontent,toapproximately2g/kWhat50%and75%load氮氧化物下降的幅度几乎与含水量同步，在50%和75%负荷下约为2g/kWh•Similarsystemisbeingplannedforfueloil,sotheTierIIIcomplianttechnologywillbeavailableasadualfuelsolution目前正计划对燃油使用类似的系统，从而实现满足欧洲氮氧化物第三阶段排放要求的技术，获得双燃料解决方案•R&Dtestingcompleted-servicetestisunderpreparation研发测试已完成—运用测试正在准备中Source:MAN来源：MANWWW.METHANOL.ORGCONVENTIONALMeOHEMISSIONSSCORECARD传统的甲醇船舶排放评价ParticulateMatter颗粒物Methanol(MeOH)achieveslowemissions&actsasabridgeinloweringCO2inthefuture(renewable/biomethanol)甲醇(MeOH)可实现低排放，可作为一种优选方式在未来降低CO2排放（可再生/生物甲醇）WWW.METHANOL.ORGGLOBALPORTTERMINALAVAILABILITY('000MT)–ALREADY97PORTSCONFIRMED全球港口码头吞吐量（'000公吨）BlackSeaRussiaEastEuropeandBalticCanada加拿大Region黑海俄罗斯东欧和波罗的海地区US-WestCoastNorthWestEuropeEastChina美国―西海岸欧洲西北部中国东部地区US-GulfCoastSouthernEuropeSouthChina美国-墨西哥湾海岸欧洲南部中国南部地区LatinAmerica-PacificUS-EastCoastKorea,JapanCoast美国-东海岸韩国、日本SouthEastAsia拉丁美洲-太平洋海岸Africa–MedIndiaandAustralia非洲一地中海印度东南亚及澳大利亚OtherMiddleEastWWW.METHANOL.ORG其他中东地区LatinAmerica-OtherAfricaAtlanticCoast其他非洲地区拉丁美洲-大西洋海岸MiddleEast–Med中东—地中海METHANEX10-YRAVGREALIZEDPRICEUS$/tonne美元/公吨梅赛尼斯公司10年平均实际价格10-yraveragerealizedpriceUS$345/tonne10年平均实际价格345美元/公吨•MethanexpostsreferencepricesmonthlyinAsiaandNorthAmericaandquarterlyinEuropeMethanex在亚洲和北美每月发布参考价格，在欧洲每季度发布参考价格•Realizedpricingislowerthanreferencepricesduetodiscountsspecifiedincontracts•由于合同中会提供一定的折扣，实际价格低于参考价格Source:MethanexCorporation来源：梅赛尼斯公司WWW.METHANOL.ORGMETHANOLFUELLEDVESSELSANDPILOTS甲醇船舶及试点项目DUALFUEL双燃料FUELCELLPROJECTR&D可行性研究燃料电池Quantity数量7+41121+4FerryVesselChemicalROPAXPilotTouristCruiseships,Type船型tankersferryboatboatfishingboats,barges,dredges,othersSUMMETH/MARTEC,LeanMOL,W-L,Ships,Methaship,BillionMarinvest,Methanex,MI/SMAInnogyMiles1,FiTech2,IWAI3,ScandiNaosHTWGOwner船东Mitsui,StenaLineKonstanzVikingLinePCGProductVessel4,OIIO,NYKNTU2,GMM,Fastwater,PortofRotterdamBarge,Jupiter,Paxell,MethanexFishing5EngineType2stroke4strokehighspeedSerenergyfuelcellSIhybrid,dualfuel,etc.发动机型号MANWärtsilaScania,stacksWeichaiDesign设计newbuildretrofitretrofitretrofitretrofitnewbuild&retrofitAllprojectsarebasedintheEUunlessnotedotherwise1China/SG,2EU/China/SG,3India,4Malaysia,5ChinaWWW.METHANOL.ORGSAFERFORTHEENVIRONMENT在环境中更安全CONCENTRATION（致死浓度）LC50半数致死浓度,LC=LETHALConcentrationinwater,atwhichhalfthepopulationdiedwithinspecifiedtestduration在规定的测试时间内，致半数海洋生物死亡的水中浓度BetterthanDieselbyafactorof240times比柴油优240倍Methanol[1]Methane[5]HeavyFuelOil[3]Diese[4]Gasoline[2]15,400(mg/l)Met甲ha烷ne[5]Heavy重F油uelOil[3]D柴ie油sel[4]Gas汽ol油ine[2]甲醇[1]49,9(mg/l)79(mg/l)65(mg/l)8,2(mg/l)15,400(mg/l)BetterthanGasolinebyafactorof1900times比汽油优1900倍[1]ECHA,EuropeanChemicalsAgency,registrationdossierMethanol[2]Petrobras/StatoilASA,SafetyDataSheet,ECHAregistrationdossierGasoline[3]GKG/A/SDanskShell,SafetyDataSheet[4]ECHA,EuropeanChemicalsAgency,registrationdossierDiesel[5]ECHA,EuropeanChemicalsAgency,registrationdossierMethaneAdditionalSource:Meyer-Werft其他来源：Meyer-WerftWWW.METHANOL.ORG国际海事组织确认甲燃料电池修订案醇为船舶燃料乙/甲醇转介其他小组委员会低闪点柴油乙/甲醇乙/甲醇燃料电池燃料电池低闪点柴油低闪点柴油oAfterexpected修订案ApprovalbyMSC102批准采纳inMay/June,2020,InterimGuidelinesmaybegintobeAdoptedattheflagstatelevelwith乙/甲醇theunderstandingthat燃料电池additionalamendments低闪点柴油乙/甲醇willbeadded燃料电池燃料电池临时指南草案生效低闪点柴油乙/甲醇低闪点柴油修订案确认案转介其他小组委员会WWW.METHANOL.ORGMETHANOLFORFUELCELLS燃料电池甲醇燃料WWW.METHANOL.ORGNetvolumetricenergydensity//[MJ/kg]PRACTICALLIQUIDFUELDominantglobaltransportationfuels,highenergy净体积能量密度/[MJ/kg]density实用的液体燃料主导交通全球燃料，能源密度高APractiaclalternative实用的代替方案Diesel柴油Gasoline汽油Ethanol乙醇Methanol甲醇200barMethane200bar甲烷Batteries电池Netgravimetricenergydensity/[MJ/kg]净质量能量密度/[MJ/kg]LowenergydensityHighonboardstoragecosts低能量密度车船等存储成本高WWW.METHANOL.ORG燃料电池如何工作HOWAFUELCELLWORKS任何可被电力驱动的物体都可使用燃料电池Anythingthatcanbepoweredbyelectricitycanrunonafuelcell.能量效率EnergyEfficiency:35%–85%零或接近零排放ZeroorNear-ZeroEmissions长期使用经济EconomicalinLong-TermWWW.METHANOL.ORG氢气的不足HYDROGENINCOMPATIBLE•作为所有气体物质中最轻的，氢气的物理性质不能满足能源市场的要求Asthelightestofallgases,thephysicalpropertiesofhydrogenareincompatiblewiththerequirementsoftheenergymarket•仅用于制氢需约1.2单位的电能或1.4单位的天然气About1.2unitsofelectricityor1.4unitsofnaturalgasneededjusttoproducehydrogenWWW.METHANOL.ORG甲醇能源经济METHANOLENERGYECONOMY•富氢的简单分子，没有硫Simplemoleculerichinhydrogen,withnosulfur•在室温和常压下是消费者友好型燃料Consumer-friendlyliquidatroomtemperatureandambientpressure•能够从可再生资源中获取Canobtainfromrenewablesources•甲醇含氢量高，体积储氢量显著高于液氢MethanolVolumetricH2DensityhigherthanLH2甲醇Methanol:100g/L,氢H2:71g/L甲醇可以成为燃料电池和许多其他应用的通用燃料“Methanolcouldbecomeauniversalfuelforfuelcellsandmanyotherapplications.”WWW.METHANOL.ORG开创性的美国NECAR5道路测试NECAR5RECORDROADTRIP2002年6月4日：戴姆勒克莱斯勒公司的NECAR5项目成为首个完成由旧金山到华盛顿特区的横穿美国里程的燃料电池车辆June4,2002:DaimlerChrysler’sNECAR5becamethefirstfuelcellvehicletocompleteacross-countrytrip,fromSanFranciscotoWashington,D.C.WWW.METHANOL.ORG甲醇加注站VS氢加注站METHANOLVSHYDROGENSTATION•2002年4月：加州燃料电池合作组织开放甲醇加注站April24,2002:CaliforniaFuelCellPartnershipopensmethanolfuelingstation•2000加仑（约7.4立方米）的地面储罐，价格仅4.5万美元2,000-gallonabove-groundtankanddispenserjust$45,000•需要一个10层（建筑物）高，10米直径的储罐来满足常规加油站的液体加注能力A10storytankwitha10meterdiameterwouldbeneededtomatchliquidrefuelingcapacityattheaveragefuelingstationWWW.METHANOL.ORG规模化甲醇加注站与加氢站对比StationtoStation（美国）基础设施建设成本比较ComparativeInfrastructureCAPEX液体燃料电氢LiquidFuelsElectricityHydrogen典型站每日实现的英里数500,0004,8009,000DailyMilesEnabledbyTypicalCurrentStation实现相同能量吞吐能力需要的站数量110456StationsNeededtoAchieveEnergyEquivalentThroughputCapacity每种站的建设成本$200,000$80,000$2,500,000CostPerCurrentStation$200,000$8,300,000$139,000,000同等能力的站点建设成本CostPerEquivalentStation10000座站的全国网络20亿美元830亿美元1.4万亿美元Costfor10,000StationNationalNetwork$2bln$83bln$1.4tln假设条件：加油站加注能力：600,000加仑/月，平均25mpg，相当于1000公斤/小时充电站充电能力：200英里/电动车，需要1.5小时充满，每个站2个充电桩，一天加注24俩车小型氢气加注站能力：150kg/天，60英里/公斤WWW.METHANOL.ORGGlobalTransportationFuelProgress全球燃料应用进展（燃料电池）MSFВЕДЕТСВОЮДЕЯТЕЛЬНОСТЬВБОЛЕЕЧЕМ60СТРАНАХМИРАDenmark丹麦–MethanolFuelCellforEVrangeextension用于电动汽车续航里程的甲醇燃料电池–Europe’sfirstmethanolfillingstationinAalborg,Denmark(Aug.2015)欧洲首个甲醇加注站—丹麦奥尔堡（2015年8月）China中国–PalcanCooperationwithDongfengonFCLorrywithproductcertificate博能集团同东风商用车合作甲醇燃料点厢式货车获得公告–ChinesegovernmentsupportingFCvehiclesandmax.500KRMBsubsidy国家财政对燃料电池车支持并给与最高50万元补贴–OthermethanolfuelcellcompaniescooperatingwithOEMsinChinatodevelopmentmoremodels其他甲醇燃料电池公司正同国内汽车合作开发多种车型Germany德国–MSInnogyusingmethanolfuelcellforpassengershipMSInnogy公司使用甲醇燃料电池作为客运船舶动力–GreenmethanolproducedfromCO2使用CO2生产的绿色甲醇WWW.METHANOL.ORG甲醇燃料电池超级跑车SUPERCARWITHMETHANOLFUELCELLSWWW.METHANOL.ORGTHANKYOU谢谢WWW.METHANOL.ORG